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A01 石田 真敏

 石田 真敏

公募 A01

所 属

九州大学 大学院工学府

役 職

助教

連絡先

ishida.masatoshi.686@m.kyushu-u.ac.jp

研究室HP

http://www.cstf.kyushu-u.ac.jp/~furutalab/

研究課題

π共役構造を鍵とした配位アシンメトリー錯体分子の幾何構造機能の創出

研究内容

本新学術領域研究では、柔軟なπ共役系オリゴピロール骨格が成すトポロジカルな幾何構造(ノット、カテナン、メビウスリング等)を基盤とした巨大π共役系キラル金属錯体の創製を行う。これらのアシメントリーなπ共役配位構造体の形状に由来する光・電子・磁気特性に着目したナノキラル素子材料の開発を目指す。具体的には、天然色素であるポルフィリン構造に倣ったπ共役オリゴピロール分子群を基本骨格として、捻じれ構造を複数の金属配位により精密制御することで、ヘリカル配位アシンメトリーに基づく螺旋状電導現象の実証について検討する。さらにオリゴピロールπ共役部分骨格を構成要素とするπ共役中空分子を鍵構造として、空間結合インターロック分子の創製を検討する。π共役リング間の空間的相互作用を介した新たな光物性の評価を行う。

専門分野

構造有機化学、錯体化学、理論化学

研究キーワード

π共役、芳香族性、トポロジカルキラリティ-、空間結合、近赤外光

研究業績

2020

[31] NH Tautomerism of N-Confused Porphyrin: Solvent/Substituent Effects and Isomerization Mechanism,
Tomoya Ishizuka; Ryuichi Sakashita; Osamu Iwanaga; Tatsuki Morimoto; Shigeki Mori; Masatoshi Ishida; Motoki Toganoh; Kiyonori Takegoshi; Atsuhiro Osuka; Hiroyuki Furuta, J. Phys. Chem. A, 124, 25, 5756 - 5769, 2020
DOI: 10.1021/acs.jpca.0c04779.
[30] Semiconducting Supramolecular Organic Frameworks Assembled from a Near-Infrared Fluorescent Macrocyclic Probe and Fullerenes,
Ramandeep Kaur; Sajal Sen; Mads Christian Larsen; Luciana Tavares; Jakob Kjelstrup-Hansen; Masatoshi Ishida; Anna Zieleniewska; Vincent M. Lynch; Steffen Bähring; Dirk M. Guldi; Jonathan L. Sessler; Atanu Jana, J. Am. Chem. Soc., 142, 26, 11497 - 11505, 2020
DOI: 10.1021/jacs.0c03699.
[29] Near-Infrared-III Absorbing and Emitting Dyes: Energy Gap Engineering of Expanded Porphyrinoids via Metallation,
Yue Wang ; Koki Ogasahara; Daisuke Tomihama; Radomir Mysliborski; Masatoshi Ishida; Yongseok Hong; Yusuke Notsuka ; Yoshihisa Yamaoka; Tomotaka Murayama ; Atsuya Muranaka; Masanobu Uchiyama; Shigeki Mori; Yuhsuke Yasutake ; Susumu Fukatsu; Dongho Kim; Hiroyuki Furuta, Angew. Chem. Int. Ed., , 2020
DOI: 10.1002/anie.202006026.
[28] Synthesis, Photophysical Properties and Computational Studies of beta-Substituted Porphyrin Dyads,
Praseetha E. Kesavan; Vijayalakshmi Pandey; Masatoshi Ishida; Hiroyuki Furuta; Shigeki Mori; Iti Gupta, Chem. Asian. J., 15, 13, 2015 - 2028, 2020
DOI: 10.1002/asia.202000463.
[27] Copper 1,19-Diaza-21,24-dicarbacorrole: A Corrole Analogue with an N-N Linkage Stabilizes a Ground-State Singlet Organocopper Species,
Biju Basumatary ; Ikuho Hashiguchi ; Shigeki Mori; Soji Shimizu; Masatoshi Ishida; Hiroyuki Furuta, Angew. Chem. Int. Ed., , 2020
DOI: 10.1002/anie.202005167.
[26] Synthesis of a Black Dye with Absorption Capabilities Across the Visible-to-Near-Infrared Region: A MO-Mixing Approach via Heterometal Coordination of Expanded Porphyrinoid,
Yue Wang; Hiroto Kai; Masatoshi Ishida; Sabapathi Gokulnath; Shigeki Mori; Tomotaka Murayama; Atsuya Muranaka; Masanobu Uchiyama; Yuhsuke Yasutake; Susumu Fukatsu; Yusuke Notsuka; Yoshihisa Yamaoka; Mamiko Hanafusa; Michito Yoshizawa; Gakhyun Kim; Dongho Kim; Hiroyuki Furuta, J. Am. Chem. Soc., 142, 14, 6807 - 6813, 2020
DOI: 10.1021/jacs.0c01824.
[25] Regioselectively α- and β-Alkynylated BODIPY Dyes via Gold(I)-Catalyzed Direct C-H Functionalization and Their Photophysical Properties,
Takahide Shimada; Shigeki Mori; Masatoshi Ishida; Hiroyuki Furuta, Beilstein J. Org. Chem., 16, 587 - 595, 2020
DOI: 10.3762/bjoc.16.53.
[24] Bis-Metal Complexes of Doubly N-Confused Dioxohexaphyrins as Potential Near-Infrared-II Photoacoustic Dyes,
Keito Shimomura; Hiroto Kai; Yuma Nakamura; Yongseok Hong; Shigeki Mori; Koji Miki; Kouichi Ohe; Yusuke Notsuka; Yoshihisa Yamaoka; Masatoshi Ishida; Dongho Kim; Hiroyuki Furuta, J. Am. Chem. Soc., 142, 9, 4429 - 4437, 2020
DOI: 10.1021/jacs.9b13475.
[23] Tungsten(VI) Complex of N‐Fused Porphyrin Absorbing Near‐Infrared Light beyond 1000 nm,
Takaaki Yamamoto ; Jibin Alex Abraham; Shigeki Mori; Motoki Toganoh; Soji Shimizu; Masatoshi Ishida ; Hiroyuki Furuta, Chem. Asian. J., 15, 6, 748 - 752, 2020
DOI: 10.1002/asia.202000014.
[22] Tripyrrin-armed isosmaragdyrins: synthesis, heterodinuclear coordination, and protonation-triggered helical inversion,
Chengjie Li; Kai Zhang; Masatoshi Ishida; Qizhao Li; Keito Shimomura; Glib Baryshnikov; Xin Li; Mathew Savage; Xin-Yan Wu; Sihai Yang; Hiroyuki Furuta; Yongshu Xie, Chem. Sci., 11, 2790 - 2795, 2020
DOI: 10.1039/C9SC06197E.
[21] N-Confused Phlorin-Prodigiosin Chimera: meso-Aryl Oxidation and π-Extension Triggered by Peripheral Coordination,
Guangxian Su; Qizhao Li; Masatoshi Ishida; Chengjie Li; Feng Sha; Xinyan Wu; Glib Baryshnikov ; Lu Wang; Dawei Li; Hans Ågren; Hiroyuki Furuta ; Yongshu Xie , Angew. Chem. Int. Ed., 59, 4, 1537 - 1541, 2020
DOI: 10.1002/anie.201913290.

2019

[20] Bis‐Copper(II) Complex of Triply‐Linked Corrole Dimer and Its Dication,
Shota Ooi; Takayuki Tanaka; Takahisa Ikeue; Kazuhisa Yamasumi ; Kento Ueta; Daiki Shimizu; Masatoshi Ishida ; Hiroyuki Furuta ; Atsuhiro Osuka, Chem. Asian. J., 14, 10, 1771 - 1776, 2019
DOI: 10.1002/asia.201801467.
[19] Ruthenium N‐Confused Porphyrin: Selective Reactivity for the Ambident 2‐Heteroatom‐Substituted Pyridines Serving As Axial Ligands,
Takaaki Miyazaki ; Kazuki Fukuyama ; Shunichi Mashita; Yuya Deguchi ; Takaaki Yamamoto ; Masatoshi Ishida; Shigeki Mori ; Hiroyuki Furuta, ChemPlusChem, 84, 6, 603 - 607, 2019
DOI: 10.1002/cplu.201800630.
[18] Doubly N‐Confused Calix[6]phyrin Bis‐Organopalladium Complexes: Photostable Triplet Sensitizers for Singlet Oxygen Generation,
Poornenth Pushpanandan ; Dong‐Hoon Won ; Shigeki Mori ; Yuhsuke Yasutake ; Susumu Fukatsu; Masatoshi Ishida ; Hiroyuki Furuta, Chem. Asian. J., 14, 10, 1729 - 1736, 2019
DOI: 10.1002/asia.201801671.
[17] Skeletal Rearrangement of Twisted Thia-Norhexaphyrin: Multiply Annulated Polypyrrolic Aromatic Macrocycles,
Qizhao Li; Masatoshi Ishida; Hiroto Kai ; Tingting Gu ; Chengjie Li; Xin Li; Glib Baryshnikov; Xu Liang; Weihua Zhu ; Hans Ågren ; Hiroyuki Furuta; Yongshu Xie, Angew. Chem. Int. Ed., 58, 18, 5925 - 5929, 2019
DOI: 10.1002/anie.201900010.
[16] Regioselectively Halogenated Expanded Porphyrinoids as Building Blocks for Constructing Porphyrin–Porphyrinoid Heterodyads with Tunable Energy Transfer,
Qizhao Li; Chengjie Li; Jinseok Kim; Masatoshi Ishida; Xin Li; Tingting Gu; Xu Liang; Weihua Zhu; Hans Ågren; Dongho Kim; Hiroyuki Furuta; Yongshu Xie, J. Am. Chem. Soc., 141, 13, 5294 - 5302, 2019
DOI: 10.1021/jacs.8b13148.
[15] Hierarchical Hybrid Metal–Organic Frameworks: Tuning the Visible/Near-Infrared Optical Properties by a Combination of Porphyrin and Its Isomer Units,
Yufeng Yang; Masatoshi Ishida; Yuhsuke Yasutake; Susumu Fukatsu; Chihoko Fukakusa; Masa-aki Morikawa; Teppei Yamada; Nobuo Kimizuka; Hiroyuki Furuta, Inorg. Chem., 58, 7, 4647 - 4656, 2019
DOI: 10.1021/acs.inorgchem.9b00251.
[14] Planar Antiaromatic Core‐Modified 24π Hexaphyrin(1.0.1.0.1.0) and 32π Octaphyrin(1.0.1.0.1.0.1.0) Bearing Alternate Hybrid Diheterole Units,
Jayaprakash Ajay; Sriram Shirisha ; Masatoshi Ishida; Kosuke Ito ; Shigeki Mori ; Hiroyuki Furuta ; Sabapathi Gokulnath, Chem. Eur. J., 25, 11, 2859 - 2867, 2019
DOI: 10.1002/chem.201805861.
[13] Phosphorescent Rhenium-Dipyrrinates: Efficient Photosensitizers for Singlet Oxygen Generation,
Neha Manav; Praseetha E. Kesavan; Masatoshi Ishida; Shigeki Mori; Yuhsuke Yasutake; Susumu Fukatsu; Hiroyuki Furuta; Iti Gupta, Dalton Trans., 48, 2467 - 2478, 2019
DOI: 10.1039/C8DT04540B.

2018

[12] Functionalised tetrathiafulvalene- (TTF-) macrocycles: recent trends in applied supramolecular chemistry,
Atanu Jana; Steffen Bähring; Masatoshi Ishida; Sébastien Goeb; David Canevet; Marc Sallé; Jan O. Jeppesen; Jonathan L. Sessler, Chem. Soc. Rev., 47, 5614 - 5645, 2018
DOI: 10.1039/C8CS00035B.
[11] Ground-State Copper(III) Stabilized by N-Confused/N-Linked Corroles: Synthesis, Characterization, and Redox Reactivity,
Yogesh Kumar Maurya; Katsuya Noda; Kazuhisa Yamasumi; Shigeki Mori; Tomoki Uchiyama; Kazutaka Kamitani; Tomoyasu Hirai; Kakeru Ninomiya; Maiko Nishibori; Yuta Hori; Yoshihito Shiota; Kazunari Yoshizawa; Masatoshi Ishida; Hiroyuki Furuta, J. Am. Chem. Soc., 140, 22, 6883 - 6892, 2018
DOI: 10.1021/jacs.8b01876.
[10] Two Discrete RuCp* (Cp* = Pentamethylcyclopentadienyl) Binding Modes of N-Confused Porphyrins: Peripheral p Complex and Sitting Atop Ruthenocenophane Complex by Skeletal Transformation,
Takaaki Yamamoto; Koki Mitsuno; Shigeki Mori; Shuhei Itoyama; Yoshihito Shiota; Kazunari Yoshizawa; Masatoshi Ishida; Hiroyuki Furuta , Chem. Eur. J., 24, 6742 - 6746, 2018
DOI: 10.1002/chem.201801237.
[9] Switch-ON Near IR Fluorescent Dye Upon Protonation: Helically Twisted Bis(Boron Difluoride) Complex of π-Extended Corrorin,
Yutaka Hisamune; Taeyeon Kim; Keiichi Nishimura; Masatoshi Ishida; Motoki Toganoh; Shigeki Mori; Dongho Kim; Hiroyuki Furuta, Chem. Eur. J., 24, 4628 - 4634, 2018
DOI: 10.1002/chem.201705516.
[8] N-Confused Porphyrin Metal Complexes with an Axial Pyridine Directly Tethered from an Inner Carbon: A Bioinspired Ligand as Versatile Platform for Catalysis,
Takaaki Miyazaki; Takaaki Yamamoto; Shunichi Mashita; Yuya Deguchi; Kazuki Fukuyama; Masatoshi Ishida; Shigeki Mori; Hiroyuki Furuta, Eur. J. Inog. Chem., 2018, 203 - 207, 2018
DOI: 10.1002/ejic.201701494.

2017

[7] Zirconium-based Metal-Organic Frameworks with N-Confused Porphyrins: Synthesis, Structures, and Optical Properties,
Yufeng Yang; Ryuichi Sakashita; Kazuhisa Yamasumi; Masatoshi Ishida; Teppei Yamada; Hiroyuki Furuta, Chem. Lett., 46, 8, 1230 - 1232, 2017
DOI: 10.1246/cl.170461.
[6] Stereoretentive Ligand Exchange Reactions of N-Fused Porphyrin Ruthenium(II) Complexes,
Hideaki Matsuo; Motoki Toganoh; Masatoshi Ishida; Shigeki Mori; Hiroyuki Furuta, Inorg. Chem., 56, 13842 - 13851, 2017
DOI: 10.1021/acs.inorgchem.7b01972.
[5] Singly and Doubly N-Confused Calix[4]phyrin Organoplatinum(II) Complexes as Near-IR Triplet Sensitizers,
Poornenth Pushpanandan; Yogesh K. Maurya; Toshihiro Omagari; Ryuji Hirosawa; Masatoshi Ishida; Shigeki Mori; Yuhsuke Yasutake; Susumu Fukatsu; John Mack; Tebello Nyokong; Hiroyuki Furuta, Inorg. Chem., 56, 12572 - 12580, 2017
DOI: 10.1021/acs.inorgchem.7b02047.
[4] Bis-Copper(II)/π-Radical Multi-Heterospin System with Non-innocent Doubly N-Confused Dioxohexaphyrin(1.1.1.1.1.0) Ligand,
Kazuhisa Yamasumi; Keiichi Nishimura; Yutaka Hisamune; Yusuke Nagae; Tomoki Uchiyama; Kazutaka Kamitani; Tomoyasu Hirai; Maiko Nishibori; Shigeki Mori; Satoru Karasawa; Tatsuhisa Kato; Ko Furukawa; Masatoshi Ishida; Hiroyuki Furuta, Chem. Eur. J., 23, 15322 - 15326, 2017
DOI: 10.1002/chem.201704321.
[3] Doubly N-Confused [36]Octaphyrin(1.1.1.1.1.1.1.1): Isomerization, Bis-Metal Coordination, and Topological Chirality,
Koki Mitsuno; Takafumi Yoshino; Iti Gupta; Shigeki Mori; Satoru Karasawa; Masatoshi Ishida; Hiroyuki Furuta, Angew. Chem. Int. Ed., 56, 14252 - 14256, 2017
DOI: 10.1002/anie.201708253.
[2] Organometallic Group 11 (CuIII, AgIII, AuIII) Complexes of a trans-Doubly N-Confused Porphyrin: An “Expanded Imidazole” Structural Motif,
Jiaying Yan; Yufeng Yang; Masatoshi Ishida; Shigeki Mori; Bao Zhang; Yaqing Feng; Hiroyuki Furuta, Chem. Eur. J., 23, 47, 11375 - 11384, 2017
DOI: 10.1002/chem.201701958.
[1] Tautomerism-Induced Cis–Trans Isomerization of Pyridylethenyl N-Confused Porphyrin,
Ryuichi Sakashita; Yasutaka Oka; Hisanori Akimaru; Praseetha E. Kesavan; Masatoshi Ishida; Motoki Toganoh; Tomoya Ishizuka; Shigeki Mori; Hiroyuki Furuta, J. Org. Chem., 82, 16, 8686 - 8696, 2017
DOI: 10.1021/acs.joc.7b01770.