menu

A01 Koji Yamamoto

Koji Yamamoto

Participating A01

Affiliation

School of Materials and Chemical Technology, Tokyo Institute of Technology

Position

Assistant Professor

Contact

kyama@apc.titech.ac.jp

HP

http://www.apc.titech.ac.jp/~tmurahashi/index.html

Research Project

Development of Coordination Asymmetry Based on Sandwich Structures

Co-Investigator

Tetsuro Murahashi (Professor, School of Materials and Chemical Technology, Tokyo Institute of Technology)

Abstract

In this project, we develop Coordination Asymmetry using multinuclear sandwich motif. The research includes studies of (1) asymmetric oligomerization of mixed-metal sandwich cluster (2) development of chiral metalloligand with sandwich structures (3) chiral recognition and asymmetric catalysis by asymmetric sandwich complexes. Chiral recognition or asymmetric catalysis by using chiral sandwich complexes are also investigated.

Research Areas

Coordination Chemistry, Organometallics, Catalysis

Keywords

Sandwich compound, Cluster, Oligomerization, Molecular Recognition

2019

[5] Extended Open-Chain Polyenides as Versatile Delocalized Anion Ligands for Metal Chain Clusters,
Mitsuki Yamashita; Yuna Kawasumi; Yuki Tachibana; Shinnosuke Horiuchi; Koji Yamamoto; Tetsuro Murahashi, Chem. Eur. J., 25, 1212 - 1216, 2019
DOI: 10.1002/chem.201805800.

2018

[4] Three-Dimensional Sandwich Nanocubes Composed of 13-Atom Palladium Core and Hexakis-Carbocycle Shell,
Masahiro Teramoto; Kosuke Iwata; Hiroshige Yamaura; Kenta Kurashima; Koshi Miyazawa; Yuki Kurashige; Koji Yamamoto; Tetsuro Murahashi, J. Am. Chem. Soc., 140, 40, 12682 - 12686, 2018
DOI: 10.1021/jacs.8b07430.
[3] Bimodal Coordination of Fused Arenes to a Pd3 Cluster Site,
Tsuyoshi Sugawa; Koji Yamamoto; Tetsuro Murahashi, Chem. Commun., 5875 - 5878, 2018
DOI: 10.1039/c8cc02880j.
[2] Contiguous Multiple π-Coordination of π-Conjugated Polyenes: Bonding Nature and Charge Delocalization Behaviour of Polyene-(Palladium Chain) Sandwich Cluster,
Mariko Yamane; Mitsuki Yamashita; Koji Yamamoto; Tetsuro Murahashi, Phys. Chem. Chem. Phys., 20, 6, 4287 - 4296, 2018
DOI: 10.1039/C7CP06735F.

2017

[1] Bridging Coordination of Vinylarenes to Pd3- or Pd4 Cluster Sites,
Yuki Ishikawa; Seita Kimura; Koji Yamamoto; Tetsuro Murahashi, Chem. Eur. J., 23, 57, 14149 - 14152, 2017
DOI: 10.1002/chem.201703023.