A01 Naokazu Kano
Naokazu Kano |
Participating A01 | ||
Affiliation |
Department of Chemistry, Gakushuin University |
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Position |
Professor |
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Contact |
naokazu.kano@gakushuin.ac.jp |
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HP |
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Research Project |
Creation of Coordination-Asymmetric and Functional Molecules Based on a Bond between Highly Coordinated Main Group Elements |
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Abstract |
Several bonds between the second-row elements work as functional groups in organic chemistry. Instead of such conventional bonds, we create new chemical bonds between two different elements in a highly coordinated state or hypervalent state. The coordination number of the central main-group-element atoms in the new bonds are oncreased, and formation of many potential diastereomers are expected. We develop selective and efficient synthetic methods for some specific isomers among them. We choose pentacoordinated silicon or phosphorus, the third-row elements, for one of the element which forms the bond, and boron or aluminum, the group 13 elements, for the counterpart. Such the compounds bearing the new bond should be unique Lewis acids which have a hypervalent moiety bound to the Lewis acid center. They are expected to be functional coordination-asymmetric molecules. |
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Research Areas |
Main Group Chemistry, Structural Organic Chemistry, Organic Reactions |
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Keywords |
Main Group Element, Chemical Bond, Functional Group, Highly Coordinated Compound, Hypervalent Compound |
2021
Tatsuya Morofuji; Yu Matsui; Misa Ohno; Gun Ikarashi; Naokazu Kano, Chem. Eur. J., , 2021
DOI: 10.1002/chem.202005300.
2020
Nathan J. O’Brien; Yoichiro Koda; Hiroaki Maeda; Naokazu Kano, Polyhedron, 185, 114841, 2020
DOI: 10.1016/j.poly.2020.114841.
Alexander A. Vinogradov; Morito Shimomura; Naokazu Kano; Yuki Goto; Hiroyasu Onaka; Hiroaki Suga, J. Am. Chem. Soc., 142, 32, 13886 – 13897, 2020
DOI: 10.1021/jacs.0c05541.
Tatsuya Morofuji; Tatsuki Yoshida; Ryosuke Tsutsumi; Masahiro Yamanaka; Naokazu Kano, Chem. Commun., 56, 90, 13995 – 13998, 2020
DOI: 10.1039/D0CC05830K.
Nathan J. O’Brien; Naokazu Kano; Nizam Havare; Ryohei Uematsu; Romain Ramozzi; Keiji Morokuma, Eur. J. Inog. Chem., 2020, 20, 1995 – 2003, 2020
DOI: 10.1002/ejic.202000229.
Tatsuya Morofuji; Gun Ikarashi; Naokazu Kano, Org. Lett., 22, 7, 2822 – 2827, 2020
DOI: 10.1021/acs.orglett.0c00822.
Gun Ikarashi; Tatsuya Morofuji; Naokazu Kano, Chem. Commun., 56, 69, 10006 – 10009, 2020
DOI: 10.1039/d0cc03286g.
2019
Tatsuya Morofuji; Hanae Kinoshita; Naokazu Kano, Chem. Commun., 55, 59, 8575 – 8578, 2019
DOI: 10.1039/C9CC04012A.
2017
Naokazu Kano; Nathan J. O’Brien; Ryohei Uematsu; Romain Ramozzi; Keiji Morokuma, Angew. Chem. Int. Ed., 56, 21, 5882 – 5885, 2017
DOI: doi.org/10.1002/anie.201701718.