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A01 Shinnosuke Horiuchi

Shinnosuke Horiuchi

 Participating A01

Affiliation

Graduate School of Engineering, Nagasaki University

Position

Assistant Professor

Contact

shoriuchi@nagasaki-u.ac.jp

HP

http://www.cms.nagasaki-u.ac.jp/lab/sakutai/index_e.htm

Research Project

Development of Asymmetry Chemistry in Emissive Supramolecular Complexes Constructed by Noncovalent Interactions and Reversible Bond Formation

Abstract

In nature, biomolecules constructed by noncovalent interactions and reversible bond formation show sophisticated molecular system that can not be achieved by artificial molecules. The understanding of self-assembly process in nature will lead us to obtain new types of supramolecular complexes that can show unusual structure, reactivity, and physical properties. This project aims at formations of new types of emissive supramolecular complexes via noncovalent interactions and reversible bond formation. Small structural differences in the components can be amplified through the self-assembly process, giving rise to form unusual self-assembled structures. This strategy will be promising to obtain asymmetrical supramolecular complexes and observe unusual physical properties derived from their asymmetric structures.

Research Areas

Supramolecular Chemistry, Coordination Chemistry, Photo Chemistry

Keywords

Emissive Supramolecular Complex, Self-Assembly, Noncovalent Interaction

2021

[11] Multinuclear Ag Clusters Sandwiched by Pt Complex Units: Fluxional Behavior and Chiral-at-Cluster Photoluminescence,
S. Horiuchi; S. Moon; A. Ito; J. Tessarolo; E. Sakuda; Y. Arikawa; G. H. Clever; K. Umakoshi, Angew. Chem. Int. Ed., 60, 19, 10654 – 10660, 2021
DOI: 10.1002/anie.202101460.
[10] Emissive Supramolecular Systems Based on Reversible Bond Formation and Noncovalent Interactions,
S. Horiuchi; K. Umakoshi, The Chemical Record, 21, 3, 469 – 479, 2021
DOI: 10.1002/tcr.202000125.
[9] Bridging-Arylene Effects on Spectroscopic and Photophysical Properties of Arylborane–Dipyrrinato Zinc(II) Complexes,
K. Takaki; E. Sakuda; A. Ito; S. Horiuchi; Y. Arikawa; K. Umakoshi, RSC Adv., 11, 6259 – 6267, 2021
DOI: 10.1039/d0ra09029h.
[8] A Heteropolynuclear Pt-Ag System Having Cycloplatinated Rollover Bipyridyl Units,
S. Horiuchi; S. Tanaka; S. Moon; E. Sakuda; A. Ito; Y. Arikawa; K. Umakoshi, Inorg. Chem., 60, 3, 1513 – 1522, 2021
DOI: 10.1021/acs.inorgchem.0c02843.
[7] NO Migratory Insertion into Ruthenium–Aryl Bond with a Hydridotris(pyrazolyl)borato Ligand,
Y. Arikawa; M. Yamada; N. Takemoto; S. Horiuchi; E. Sakuda; K. Umakoshi, Organometallics, 40, 302 – 305, 2021
DOI: 10.1021/acs.organomet.0c00694.

2020

[6] Stereoisomers of Homoleptic Dipyrrinatoplatinum(II) Complexes Having Arylborane Charge-Transfer Substituents: Synthesis, Characterization and Spectroscopic Properties,
K. Takaki; E. Sakuda; A. Ito; S. Horiuchi; Y. Arikawa; K. Umakoshi, Chem. Lett., 49, 905 – 908, 2020
DOI: 10.1246/cl.200258.
[5] Photocatalytic CO2 reduction under visible-light irradiation by ruthenium CNC pincer complexes,
Y. Arikawa; I. Tabata; Y. Miura; H. Tajiri; Y. Seto; S. Horiuchi; E. Sakuda; K. Umakoshi, Chem. Eur. J., 26, 25, 5603 – 5606, 2020
DOI: 10.1002/chem.201905840.
[4] Anion-mediated encapsulation-induced emission enhancement of an IrIII complex within a resorcin[4]arene hexameric capsule,
S. Horiuchi; C. Matsuo; E. Sakuda; Y. Arikawa; G. H. Clever; K. Umakoshi, Dalton Trans., 49, 25, 8472 – 8477, 2020
DOI: 10.1039/D0DT01485K.

2019

[3] Encapsulation condition dependent photophysical properties of polypyridyl Ru(II) complexes within a hydrogen-bonded capsule,
S. Horiuchi; H. Tanaka; E. Sakuda; Y. Arikawa; K. Umakoshi, Dalton Trans., 48, 16, 5156 – 5160, 2019
DOI: 10.1039/C9DT00737G.
[2] Tunable Fullerene Affinity of Cages, Bowls and Rings Assembled by PdII Coordination Sphere Engineering,
B. Chen; S. Horiuchi; J. J. Holstein; J. Tessarolo; G. H. Clever, Chem. Eur. J., 25, 65, 14921 – 14927, 2019
DOI: 10.1002/chem.201903317.
[1] Pd(II) Coordination Sphere Engineering: Pyridine Cages, Quinoline Bowls and Heteroleptic Pills Binding One or Two Fullerenes,
B. Chen; J. J. Holstein; S. Horiuchi; W. G. Hiller; G. H. Clever, J. Am. Chem. Soc., 141, 22, 8907 – 8913, 2019
DOI: 10.1021/jacs.9b02207.