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A02 君塚 信夫

 君塚 信夫

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A02代表

所 属

九州大学 大学院工学研究院

役 職

教授

連絡先

kimizuka.nobuo.763@m.kyushu-u.ac.jp

研究室HP

http://www.chem.kyushu-u.ac.jp/~kimizuka/

研究課題

分子の自己組織化に基づくナノ界面アシンメトリー化学

研究組織

研究分担者:藤川 茂紀(九州大学カーボンニュートラル研究所・准教授)
研究協力者:山田 鉄兵(九州大学大学院工学研究院応用化学部門・准教授)
研究協力者:楊井 伸浩(九州大学大学院工学研究院応用化学部門・准教授)
研究協力者:森川 全章(九州大学大学院工学研究院応用化学部門・助教)

研究内容

本学術領域研究では、溶液中あるいは界面(表面)における金属錯体・有機分子の自己組織化に基づき、配位構造や集積構造の非対称性(アシンメトリー)を実現するための基盤技術の開発とその応用を目的とする。
具体的には、(1)分子の自己組織化に基づくキラルな配位高分子、金属ナノ粒子組織体の合成、(2)マルチスケールな配位アシンメトリー構築技術:金属錯体・高分子錯体の異方集積技術の開発、(3)電場など外場応答型の配位アシンメトリー制御技術、(4)基板表面における高分子金属錯体ナノ薄膜の液層析出合成法の開発とその構造・特性評価と機能化 をはかる。

専門分野

分子組織化学、界面化学、光機能化学

研究キーワード

自己組織化、アシンメトリー界面、アシンメトリー操作、エネルギー移動、光エネルギー変換

研究業績

2018

[28] Simple and Versatile Platform for Air-Tolerant Photon Upconverting Hydrogels by Biopolymer-Surfactant-Chromophore Co-assembly,
Pankaj Bharmoria; Shota Hisamitsu; Hisanori Nagatomi; Taku Ogawa; Masaaki Morikawa; Nobuhiro Yanai; Nobuo Kimizuka, J. Am. Chem. Soc., 140, 34, 10848 - 10855, 2018
DOI: 10.1021/jacs.8b05821.
[27] Translating MOF Chemistry into Supramolecular Chemistry: Soluble Coordination Nanofibers Showing Efficient Photon Upconversion,
Masanori. Hosoyamada; Nobuhiro. Yanai; Keisuke. Okumura; Nobuo.Kimizuka, Chem. Commun., 54, 6828 - 6831, 2018
DOI: 10.1039/C8CC01594E.
[26] Aggregation-free sensitizer dispersion in rigid ionic crystals for efficient solid-state photon upconversion and demonstration of defect effects,
Taku. Ogawa; Nobuhiro.Yanai; Saiya. Fujiwara; Thuc-Quyen. Nguyen; Nobuo. Kimizuka, J. Mater. Chem. C, 6, 21, 5565 - 5832, 2018
DOI: 10.1039/C8TC00977E.
[25] Hybridizing semiconductor nanocrystals with metal-organic frameworks for visible and near-infrared photon upconversion,
Shogo Amemori; Rakesh K. Gupta; Marcus L Böhm; James Xiao; Uyen Huynh; Tomoki Oyama; Kenji Kaneko; Akshay Rao; Nobuhiro Yanai; Nobuo Kimizuka, Dalton Trans., 47, 8590 - 8594, 2018
DOI: 10.1039/c7dt04794k.
[24] Specific Uniaxial Self-assembly of Columnar Perylene Liquid Crystals in Au Nnofin Arrays,
Daisuke Kichise; Kazuma Mase; Shigenori Fujikawa; Nobuhiro Yanai; Nobuo Kimizuka, Chem. Lett., 47, 354 - 357, 2018
DOI: 10.1246/cl.171228.
[23] Nonpolar-to-Polar Phase Transition of a Chiral Ionic Plastic Crystal and Switch of the Rotation Symmetry,
Masaya Matsuki; Teppei Yamada; Nobuhiro Yasuda; Shun Dekura; Hiroshi Kitagawa; Nobuo Kimizuka, J. Am. Chem. Soc., 140, 291 - 297, 2018
DOI: 10.1021/jacs.7b10249.
[22] Selective Ionic Conduction in Choline Iodide/Triiodide Solid Electrolyte and Its Application to Thermocells,
Tomoya Shimono; Teppei Yamada; Masa-aki Morikawa; Nobuhiro Yasuda; Tsuyohiko Fujigaya; Nobuo Kimizuka, Chem. Lett., 47, 1, 261 - 264, 2018
DOI: 10.1246/cl.171069.
[21] Stimuli-Responsive Dual-color Photon Upconversion: A Singlet-to-Triplet Absorption Sensitizer in a Soft Luminescent Cyclophane,
Kazuma Mase; Youichi Sasaki; Yoshimitsu Sagara; Nobuyuki Tamaoki; Christoph Weder; Nobuhiro Yanai; Nobuo Kimizuka, Angew. Chem. Int. Ed., 57, 2806 - 2810, 2018
DOI: 10.1003/anie.201712644.
[20] Two-dimensional structural ordering in a chromophoric ionic liquid for triplet energy migration-based photon upconversion,
Shota Hisamitsu; Nobuhiro Yanai; Hironori Kouno; Eisuke Magome; Masaya Matsuki; Teppei Yamada; Angelo Monguzzi; Nobuo Kimizuka, Phys. Chem. Chem. Phys., 20, 3233 - 3240, 2018
DOI: 10.1039/c7cp06266d.
[19] Synthesis and Electric Properties of a Two-Dimensional Metal-Organic Framework Based on Phthalocyanine,
Hisanori Nagatomi; Nobuhiro Yanai; Teppei Yamada; Kanji Shiraishi; Nobuo Kimizuka, Chem. Eur. J., 24, 1806 - 1810, 2018
DOI: 10.1002/chem.201705530.
[18] Reentrant Gel Sol Gel Transition of a Lipophilic Co(II) Coordination Polymer,
Hisanori Nagatomi; Nobuhiro Yanai; Nobuo Kimizuka, Chem. Lett., 47, 97 - 99, 2018
DOI: 10.1246/cl.170881.

2017

[17] Grain-Boundary-Free Super-Proton Conduction of a Solution-Processed Prussian-Blue Nanoparticle Film,
Kenta Ono; Manabu Ishizaki; Katsuhiko Kanaizuka; Takanari Togashi; Teppei Yamada; Hiroshi Kitagawa; Masato Kurihara, Angew. Chem. Int. Ed., 129, 20, 5623 - 5627, 2017
DOI: 10.1002/anie.201701759.
[16] Kinetically controlled crystal growth approach to enhance triplet energy migration-based photon upconversion,
Taku Ogawa; Nobuhiro Yanai; Hironori Kouno; Nobuo Kimizuka, J. Photon. Energy, 8, 2, 022003-1 - 022003-11, 2017
DOI: 10.1117/1.JPE.8.022003..
[15] Sensitizer-Free Photon Upconversion in Single-Component Brominated Aromatic Crystals,
Keisuke Okumura; Masaya Matsuki; Teppei Yamada; Nobuhiro Yanai; Nobuo Kimizuka, ChemSelect, 2, 7597 - 7601, 2017
DOI: 10.1002/slct.201701769.
[14] Applicability of MIL-101(Fe) as cathod of lithium ion battery,
Teppei Yamada; Kanji Shiraishi; Hiroshi Kitagawa; Nobuo Kimizuka, Chem. Commun., 53, 8215 - 8218, 2017
DOI: 10.1039/c7cc01712j.
[13] Triplet Sensitization by Perovskite Nanocrystals for Photon Upconversion,
Kazuma Mase; Keisuke Okumura; Nobuhiro Yanai; Nobuo Kimizuka, Chem. Commun., 53, 59, 8261 - 8264, 2017
DOI: 10.1039/c7cc03087h.
[12] Near Infrared-to-Blue Photon Upconversion by Exploiting Direct S-T Absorption of a Molecular Sensitizer,
Yoichi Sasaki; Syogo Amemori; Hiyonori Kouno; Nobuhiro Yanai; Nobuo Kimizuka, J. Mater. Chem. C, 5, 5063 - 5067, 2017
DOI: 10.1039/c7tc00827a.
[11] Photoresponsive Nanosheets of Polyoxometalates Formed by Controlled Self-Assembly Pathways,
Keita Ishiba; Takao Noguchi; Hiroaki Iguchi; Masa-aki Morikawa; Kenji Kaneko; Nobuo Kimizuka, Angew. Chem. Int. Ed., 56, 11, 2974 - 2978, 2017
DOI: 10.1002/anie.201612473.
[10] Self-Assembly of Oligo(ethylene oxide)-Linked Diammonium Ions with Polyoxometalates into Ordered Polyhedron Nanocrystals in Aqueous Media,
Keita Ishiba; Daisuke Kichise; Hiroaki Iguchi; Masa-aki Morikawa; Nobuo Kimizuka, Chem. Lett., 46, 4, 430 - 433, 2017
DOI: 10.1246/cl.161124.
[9] All-or-None Switching of Photon Upconversion in Self-Assembled Organogel Systems,
Pengfei Duan; Deepak Asthana; Takuya Nakashima; Tsuyoshi Kawai; Nobuhiro Yanai; Nobuo Kimizuka, Faraday Discuss., 196, 305 - 316, 2017
DOI: 10.1039/C6FD00170J.
[8] Introduction of Thiourea into Metal-Organic Frameworks by Immersion Technique and Their Phase Transition Characteristics,
Teppei Yamada; Yuta Kubo; Nobuo Kimizuka, Chem. Lett., 46, 1, 115 - 117, 2017
DOI: 10.1246/cl.160910.

2016

[7] A Study on Proton Conduction in a Layered Metal–Organic Framework, Rb2(adp)[Zn2(ox)3]·3H2O (adp = adipic acid, ox2- = oxalate),
Masaaki Sadakiyo; Teppei Yamada; Hiroshi Kitagawa, Inorg. Chem. Commun, 72, 138 - 140, 2016
DOI: 10.1016/j.inoche.2016.08.016.
[6] Hydrated Proton-Conductive Metal-Organic Frameworks,
Masaaki Sadakiyo; Teppei Yamada; Hiroshi Kitagawa, ChemPlusChem, 81, 691 - 701, 2016
DOI: 10.1002/cplu.201600243.
[5] Photon Upconversion and Molecular Solar Energy Storage by Maximizing the Potential of Molecular Self-Assembly,
Nobuo Kimizuka; Nobuhiro Yanai; Masa-aki Morikawa, Langmuir, 32, 12304 - 12322, 2016
DOI: 10.1021/acs.langmuir.6b03363.
[4] Hierarchical Self-Assembly of Luminescent Tartrate-Bridged Chiral Binuclear Tb(III) Complexes in Ethanol,
Jing Liu; Masa-aki Morikawa; Hairui Lei; Keita Ishiba; Nobuo Kimizuka, Langmuir, 32, 10597 - 10603, 2016
DOI: 10.1021/acs.langmuir.6b02254.
[3] Ferroelectric Coordination Polymers Self-Assembled from Mesogenic Zinc(II) Porphyrin and Dipolar Bridging Ligands,
Joseph. K.-H. Hui; Hiroyuki Kishida; Keita Ishiba; Kenta Takemasu; Masa-aki Morikawa; Nobuo Kimizuka, Chem. Eur. J., 22, 14213 - 14218, 2016
DOI: 10.1002/chem.201602175.
[2] High Proton Conductivity of Zinc Oxalate Coordination Polymers Mediated by a Hydrogen Bond with Pyridinium,
Teppei Yamada; Takuya Nankawa, Inorg. Chem., 55, 8267 - 8270, 2016
DOI: 10.1021/acs.inorgchem.6b01534.
[1] Supramolecular Thermo-Electrochemical Cells: Enhanced Thermoelectric Performance by Host–Guest Complexation and Salt-Induced Crystallization,
Hongyao Zhou; Teppei Yamada; Nobuo Kimizuka, J. Am. Chem. Soc., 138, 10502 - 10507, 2016
DOI: 10.1021/jacs.6b04923.