A02 Shuhei Furukawa

Shuhei Furukawa		Participating A02
Affiliation	Institute for Integrated Cell-Material Sciences, Kyoto University
Position	Professor
Contact	shuhei.furukawa@icems.kyoto-u.ac.jp
HP	www.furukawa.icems.kyoto-u.ac.jp
Research Project	Functionally gradient porous materials based on metal-organic polyhedra
Abstract	In this study, metal-organic polyhedra (MOP) would be assembled to create functionally gradient porous materials with anisotropic and continuous density gradient within materials. This type of materials will be fabricated by applying external stimuli to induce anisotropy at the mesoscale during the supramolecular polymerization of MOPs. The density and topology of the resulting gel network will be correlated with macroscale physical properties such as rheology. This research will lead to the development of specific functions originated from gradient materials such as anisotropic mass transport, continuous catalysis, and actuators.
Research Areas	Coordination Chemistry、Materials Science、Supramolecular Chemistry
Keywords	Porous Materials、Soft Matter、Metal-Organic Polyhedra、Supramolecular Polymerization、Colloids

2021

[24] Directional asymmetry over multiple length scales in reticular porous materials,
Alexandre Legrand; Zaoming Wang; Javier Troyano; Shuhei Furukawa, Chem. Sci., 12, 18 – 33, 2021
DOI: 10.1039/D0SC05008C.

[23] Dynamic Properties of a Flexible Metal-Organic Framework Exhibiting a Unique ‘Picture Frame’-Like Crystal Morphology,
Kenji Sumida; Nao Horike; Shuhei Furukawa, Nano. Res., 14, 432 – 437, 2021
DOI: 10.1007/s12274-020-3002-7.

2020

[22] Porous materials as carriers of gasotransmitters towards gas biology and therapeutic applications,
Arnau Carné-Sánchez; Francisco J. Carmona; Chiwon Kim; Shuhei Furukawa, Chem. Commun., 56, 9750 – 9766, 2020
DOI: 10.1039/D0CC03740K.

[21] Pseudo-5-Fold Symmetrical Ligand Drives Geometric Frustration in Porous Metal-Organic and Hydrogen Bonded Frameworks,
Frederik Haase; Gavin Craig; Mickaele Bonneau; Kunihisa Sugimoto; Shuhei Furukawa, J. Am. Chem. Soc., 142, 32, 13839 – 13845, 2020
DOI: 10.1021/jacs.0c04450.

[20] Beyond Frameworks: Structuring Reticular Materials across Nano, Meso, and Bulk Regimes,
Frederik Haase; Patrick Hirschle; Ralph Freund; Shuhei Furukawa; Zhe Ji; Stefan Wuttke, Angew. Chem. Int. Ed., 59, 50, 22350 – 22370, 2020
DOI: 10.1002/anie.201914461.

[19] Hysteresis in the gas sorption isotherms of metal–organic cages accompanied by subtle changes in molecular packing,
Gavin A. Craig; Patrick Larpent; Hinano Urabe; Alexandre Legrand; Mickaele Bonneau; Shinpei Kusaka; Shuhei Furukawa, Chem. Commun., 56, 3689 – 3692, 2020
DOI: 10.1039/D0CC00932F.

[18] Formulation of Metal–Organic Framework Inks for the 3D Printing of Robust Microporous Solids toward High-Pressure Gas Storage and Separation,
Jeremy Dhainaut; Mickaele Bonneau; Ryota Ueoka; Kazuyoshi Kanamori; Shuhei Furukawa, ACS Appl. Mater. Interface, 12, 10983 – 10992, 2020
DOI: 10.1021/acsami.9b22257.

[17] Understanding the role of linker flexibility in soft porous coordination polymers,
Yamil J. Colon; Shuhei Furukawa, Mol. Syst. Des. Eng., 5, 284 – 293, 2020
DOI: 10.1039/C9ME00117D.

2019

[16] Understanding the multiscale self-assembly of metal-organic polyhedra towards functionally graded porous gels,
Alexandre Legrand; Gavin A. Craig; Mickaele Bonneau; Saori Minami; Kenji Urayama; Shuhei Furukawa, Chem. Sci., 10, 10833 – 10842, 2019
DOI: 10.1039/C9SC04543K.

[15] Vapor‐phase linker exchange of the metal‐organic framework ZIF‐8: a solvent‐free approach to post‐synthetic modification,
Joao Marreiros; Lenz Van Dommelen; Guillaume Fleury; Rodrigo de Oliveira-Sliva; Thimothee Stassin; Paul Iacomi; Shuhei Furukawa; Dimitrios Sakellauriou; Philip Llewellyn; Maarten Roeffaers; Rob Ameloot, Angew. Chem. Int. Ed., 131, 18642 – 18646, 2019
DOI: 10.1002/anie.201912088.

[14] MOFBOTS: Metal–Organic‐Framework‐Based Biomedical Microrobots,
Xiaopu Wang; Xiang‐Zhong Chen; Carlos C. J. Alcântara; Semih Sevim; Marcus Hoop,; Anastasia Terzopoulou; Carmela de Marco; Chengzhi Hu; Andrew J. de Mello; Paolo Falcaro; Shuhei Furukawa; Bradley J. Nelson; Josep Puigmartí‐Luis; Salvador Pané, Adv. Mater., 31, 1901592, 2019
DOI: 10.1002/adma.201901592.

[13] Partially fluorinated MIL-101(Cr): from a minuscular structure modification to a huge chemical environment transformation inspected by 129Xe NMR,
Mariana L. Díaz-Ramírez; Elí Sánchez-González; J. Raziel Álvarez; Gerardo A. González Martínez; Satoshi Horike; Kentaro Kadota; Kenji Sumida; Eduardo González-Zamora; MarieAnne Springuel-Huet; Aída Gutiérrez-Alejandre; Vojtech Jancik; Shuhei Furukawa; Susumu Kitagawa; Ilich A. Ibarra; Enrique Lima, J. Mater. Chem. A, 7, 15101 – 15112, 2019
DOI: 10.1039/C9TA02237F.

[12] A Coordinative Solubilizer Method to Fabricate Soft Porous Materials from Insoluble Metal-Organic Polyhedra,
Arnau Carné-Sánchez; Gavin A. Craig; Patrick Larpent; Vincent Guillerm; Kenji Urayama; Daniel Maspoch; Shuhei Furukawa, Angew. Chem. Int. Ed., 58, 6347 – 6350, 2019
DOI: 10.1002/anie.201901668.

[11] Postsynthetic Covalent and Coordination Functionalization of Rhodium(II)-Based Metal–Organic Polyhedra,
Arnau Carné-Sánchez; Jorge Albalad; Thais Grancha; Inhar Imaz; Judith Juanhuix; Patrick Larpent; Shuhei Furukawa; Daniel Maspoch, J. Am. Chem. Soc., 141, 4094 – 4102, 2019
DOI: 10.1021/jacs.8b13593.

2018

[10] Self-assembly of metal–organic polyhedra into supramolecular polymers with intrinsic microporosity,
Arnau Carné-Sánchez; Gavin A. Craig; Patrick Larpent; Takashi Hirose; Masakazu Higuchi; Susumu Kitagawa; Kenji Matsuda; Kenji Urayama; Shuhei Furukawa, Nat. Commun., 9, 2506, 2018
DOI: 10.1038/s41467-018-04834-0.

[9] Coordination Modulation Method to Prepare New MOF-based CO-Releasing Materials,
Francisco Jesus Carmona; Carmen R Maldonado; Shuya Ikemura; Carlos C Romao; Zhehao Huang; Hongyi Xu; Xiaodong Zou; Susumu Kitagawa; Shuhei Furukawa; Elisa Barea, ACS Appl. Mater. Interface, 10, 31158 – 31167, 2018
DOI: 10.1021/acsami.8b11758.

[8] Influence of Nanoscale Structuralisation on the Catalytic Performance of ZIF-8: A Cautionary Surface Catalysis Study,
Oliver Linder-Patton; Thomas de Prinse; Shuhei Furukawa; Stephen G Bell; Kenji Sumida; Christian J Doonan; Christopher J Sumby, CrystEngComm, 20, 4926 – 4934, 2018
DOI: 10.1039/C8CE00746B.

[7] Fighting at the Interface: Structural Evolution during Heteroepitaxial Growth of Cyanometallate Coordination Polymers,
Fengqiong Li; Wei Zhang; Arnau Carne-Sanchez; Yoshihiro Tsujimoto; Susumu Kitagawa; Shuhei Furukawa; Ming Hu, Inorg. Chem., 57, 8701 – 8704, 2018
DOI: 10.1021/acs.inorgchem.8b00959.

[6] Switchable Gate-Opening Effect in Metal-Organic Polyhedra Assemblies Through Solution Processing,
Gavin A. Craig; Patrick Larpent; Shinpei Kusaka; Ryotaro Matsuda; Susumu Kitagawa; Shuhei Furukawa, Chem. Sci., 9, 31, 6463 – 6469, 2018
DOI: 10.1039/C8SC02263A.

[5] Self-assembled materials and supramolecular chemistry within microfluidic environments: from common thermodynamic states to non-equilibrium structures,
S. Sevim; A. Sorrenti; C. Franco; S. Furukawa; S. Pané; A. J. deMello; J. Puigmartí-Luis, Chem. Soc. Rev., 47, 3788 – 3803, 2018
DOI: 10.1039/C8CS00025E.

[4] Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules,
Rebeca Sola-Llano; Virginia Martínez-Martínez; Shuhei Furukawa; Yohei Takashima; Iñigo López-Arbeloa, Polymers, 10, 188, 2018
DOI: 10.3390/polym10020188.

2017

[3] Enhanced properties of metal–organic framework thin films fabricated via a coordination modulation-controlled layer-by-layer process,
Suttipong Wannapaiboon; Kenji Sumida; Katharina Dilchert; Min Tu; Susumu Kitagawa; Shuhei Furukawa; Roland A. Fischer, J. Mater. Chem. A, 5, 13665 – 13673, 2017
DOI: 10.1039/C7TA02848B.

[2] Localized Conversion of Metal–Organic Frameworks into Polymer Gels via Light-Induced Click Chemistry,
Sophia Schmitt; Stéphane Diring; Peter G. Weidler; Salma Begum; Stefan Heißler; Susumu Kitagawa; Christof Wöll; Shuhei Furukawa; Manuel Tsotsalas, Chem. Mater., 29, 14, 5982 – 5989, 2017
DOI: 10.1021/acs.chemmater.7b01677.

[1] Photopatterning of fluorescent host–guest carriers through pore activation of metal–organic framework single crystals,
I. Stassen; I. Boldog; C. Steuwe; D. De Vos; M. Roeffaers; S. Furukawa; R. Ameloot, Chem. Commun., 53, 7222 – 7225, 2017
DOI: 10.1039/C7CC02709E.