A03 植村卓史

植村卓史		計画 A03代表
所　属	東京大学大学院新領域創成科学研究科
役　職	教授
連絡先	t-uemura@edu.k.u-tokyo.ac.jp
研究室HP	http://www.k.u-tokyo.ac.jp/materials/j/lab_txt2/02/uemura.html#
研究課題	アシンメトリック配位空間を鋳型とした機能性ナノ材料創製
研究内容	本新学術領域研究では錯体化学の持つポテンシャルを最大限活用することで、多孔性金属錯体をはじめとした多彩な機能性反応場における非対称配位圏の合理的な設計を行い、新しいナノ材料創製を可能にする超空間鋳型の構築を行う。特に、非対称分子素子や界面、空間を物質創成の新しいテンプレートとして活用することで、これまでにない機能性ナノ材料の構築を試みる。ダイナミックに構造が変化しうる非対称空間をナノサイズの鋳型として用い、これらの空間情報を動的に翻訳・複製・転写することで、得られる高分子・集積材料における構造や機能の自在制御や少量の非対称性を大幅に増長できる新しい化学システムの構築を目指す。
専門分野	錯体化学、高分子化学、ナノ空間材料
研究キーワード	重合制御、鋳型合成、異方的分子集積、動的機能

研究業績

2021

[25] Metal–Organic Frameworks for Practical Separation of Cyclic and Linear Polymers,
Taku Sawayama; Yubo Wang; Tomohisa Watanabe; Masayoshi Takayanagi; Takuya Yamamoto; Nobuhiko Hosono; Takashi Uemura, Angew. Chem. Int. Ed., , 2021
DOI: 10.1002/anie.202102794.

2020

[24] Supramolecular Chiral Nanoarchitectonics,
Katsuhiko Ariga; Taizo Mori; Takashi Kitao; Takashi Uemura, Adv. Mater., 1905657, 2020
DOI: 10.1002/adma.201905657.

[23] Metal–Organic Frameworks for Macromolecular Recognition and Separation,
Nobuhiko Hosono; Takashi Uemura, Matter, 3, 3, 652 – 663, 2020
DOI: 10.1016/j.matt.2020.06.013.

[22] Unimolecularly Thick Monosheets of Vinyl Polymers Fabricated in Metal–Organic Frameworks,
Nobuhiko Hosono; Shuto Mochizuki; Yuki Hayashi; Takashi Uemura, Nat. Commun., 11, 3573, 2020
DOI: 10.1038/s41467-020-17392-1.

[21] Terminus-Dependent Insertion of Molten Poly(ethylene glycol) into a Flexible Metal–Organic Framework,
Benjamin Le Ouay; Takashi Uemura, Eur. Polym. J., 134, 5, 109855, 2020
DOI: 10.1016/j.eurpolymj.2020.109855.

[20] Carbonization of Single Polyacrylonitrile Chains in Coordination Nanospaces,
Xiyuan Zhang; Takashi Kitao; Daniele Piga; Ryoto Hongu; Silvia Bracco; Angiolina Comotti; Piero Sozzani; Takashi Uemura, Chem. Sci., 11, 10844 – 10849, 2020
DOI: 10.1039/d0sc02048f.

[19] Polymers in Metal–Organic Frameworks: From Nanostructured Chain Assemblies to New Functional Materials,
Takashi Kitao; Takashi Uemura, Chem. Lett., 49, 6, 624 – 632, 2020
DOI: 10.1246/cl.200106.

[18] Scalable and Precise Synthesis of Armchair-Edge Graphene Nanoribbon in Metal–Organic Framework,
Takashi Kitao; Michael W. A. MacLean; Kazuki Nakata; Masayoshi Takayanagi; Masataka Nagaoka; Takashi Uemura, J. Am. Chem. Soc., 142, 12, 5509 – 5514, 2020
DOI: 10.1021/jacs.0c00467.

[17] Recognition of Polymer Terminus by Metal–Organic Frameworks Enabling Chromatographic Separation of Polymers,
Nagi Mizutani; Nobuhiko Hosono; Le Ouay Benjamin; Takashi Kitao; Ryoichirou Matsuura; Takuya Kubo; Takashi Uemura, J. Am. Chem. Soc., 142, 8, 3701 – 3705, 2020
DOI: 10.1021/jacs.9b13568.

2019

[16] Enhanced mechanical properties of a metal-organic framework by polymer insertion. Chemical Communications,
Tomoya Iizuka; Kayako Honjo; Takashi Uemura, Chem. Commun., 55, 5, 691 – 694, 2019
DOI: 10.1039/C8CC08922A.

[15] Controlling the Packing of Metal-Organic Layers by Inclusion of Polymer Guests,
Benjamin Le Ouay; Hikaru Takaya; Takashi Uemura, J. Am. Chem. Soc., 141, 37, 14549 – 14553, 2019
DOI: 10.1021/jacs.9b07563.

2018

[14] A fluorescent microporous crystalline dendrimer discriminates vapour molecules,
Sae Nakajima; Ken Albrecht; Soh Kushida; Eiji Nishibori; Takashi Kitao; Takashi Uemura; Kimihisa Yamamoto; Uwe H. F. Bunz; Yohei Yamamoto, Chem. Commun., 54, 2534 – 2537, 2018
DOI: 10.1039/C7CC09342J.

[13] Polymer in MOF Nanospace: from Controlled Chain Assembly to New Functional Materials,
Benjamin Le Ouay; Takashi Uemura, Isr. J. Chem., 58, 995 – 1009, 2018
DOI: 20181031.

[12] Controlled polymerizations using metal–organic frameworks,
Shuto Mochizuki; Taashi Uemura; Takashi Uemura, Chem. Commun., 54, 11843 – 11856, 2018
DOI: doi.org/10.1039/C8CC06415F.

[11] A phase transformable ultrastable titanium-carboxylate framework for photoconduction,
Sujing Wang; Takashi Kitao; Nathalie Guillou; Mohammad Wahiduzzaman; Charlotte Martineau-Corcos; Farid Nouar; Antoine Tissot; Laurent Binet; Naseem Ramsahye; Sabine Devautour-Vinot; Susumu Kitagawa; Shu Seki; Yusuke Tsutsui; Valérie Briois; Nathalie Steunou; Guillaume Maurin; Takashi Uemura; Christian Serre, Nat. Commun., 9, 1660, 2018
DOI: 10.1038/s41467-018-04034-w.

[10] Selective Formation of End-on Orientation between Polythiophene and Fullerene Mediated by Coordination Nanospaces,
Takashi Kitao; Yotaro Sasaki; Susumu Kitagawa; Yutaka Imamura; Masahiko Tsujimoto; Shu Seki; Takashi Uemura, J. Phys. Chem. C, 122, 42, 24182 – 24189, 2018
DOI: 10.1021/acs.jpcc.8b08120.

[9] Selective sorting of polymers with different terminal groups using metal-organic frameworks,
Benjamin Le Ouay; Chikara Watanabe; Shuto Mochizuki; Masayoshi Takayanagi; Masataka Nagaoka; Takashi Kitao; Takashi Uemura, Nat. Commun., 9, 3635, , 2018
DOI: 10.1038/s41467-018-06099-z.

[8] Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels,
Shuto Mochizuki; Naoki Ogiwara; Masayoshi Takayanagi; Masataka Nagaoka; Susumu Kitagawa; Takashi Uemura, Nat. Commun., 9, 329, 2018
DOI: 10.1038/s41467-017-02736-1 .

2017

[7] Controlled Organization of Anthracene in Porous Coordination Polymers,
Takashi Kitao; Ryoto Hongu; Susumu Kitagawa; Takashi Uemura, Chem. Lett., 46, 1705 – 1707, 2017
DOI: 10.1246/cl.170741.

[6] Preparation of Polythiophene Microrods with Ordered Chain Alignment Using Nanoporous Coordination Template,
Takashi Kitao; Michael W. A. MacLean; Benjamin Le Ouay; Yotaro Sasaki; Masahiko Tsujimoto; Susumu Kitagawa; Takashi Uemura, Polym. Chem., 8, 5077 – 5081, 2017
DOI: 10.1039/c7py00309a.

[5] Hybridization of MOFs and Polymers,
Takashi Kitao; Yuanyuan Zhang; Susumu Kitagawa; Bo Wang; Takashi Uemura, Chem. Soc. Rev., 46, 3108 – 3133, 2017
DOI: 10.1039/c7cs00041c.

[4] Opening of an Accessible Microporosity in an Otherwise Nonporous Metal-Organic Framework by Polymeric Guests,
Benjamin Le Ouay; Susumu Kitagawa; Takashi Uemura, J. Am. Chem. Soc., 139, 7886 – 7892, 2017
DOI: 10.1021/jacs.7b02402.

[3] Thermal Ring-Opening Polymerization of an Unsymmetrical Silicon-Bridged [1]Ferrocenophane in Coordination Nanochannels,
Yuichiro Kobayashi; Kayako Honjo; Susumu Kitagawa; Jessica Gwyther; Ian Manners; Takashi Uemura, Chem. Commun., 53, 6945 – 6948, 2017
DOI: 10.1039/c7cc03391e.

[2] Preparation of Porous Polysaccharides Templated by Coordination Polymer with Three-Dimensional Nanochannels,
Yuichiro Kobayashi; Kayako Honjo; Susumu Kitagawa; Takashi Uemura, ACS. Appl. Mater. Interface, 9, 13, 11373 – 11379, 2017
DOI: 10.1021/acsami.6b15936.

2016

[1] Nanostructuration of PEDOT in Porous Coordination Polymers for Tunable Porosity and Conductivity,
Benjamin Le Ouay; Mickael Boudot; Takashi Kitao; Takeshi Yanagida; Susumu Kitagawa; Takashi Uemura, J. Am. Chem. Soc., 138, 32, 10088 – 10091, 2016
DOI: 10.1021/jacs.6b05552.